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- W1995751927 abstract "Abstract Four cyanido‐bridged Mn III –Cr I heterodimetallic complexes have been synthesized by the reactions of Mn III Schiff‐base complexes with the [Cr(CN) 5 (NO)] 3– building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H 2 O) 2 ][Mn 2 (5‐Cl‐salen) 2 (H 2 O) 1.5 Cr(CN) 5 (NO)] ( 1 ) has a trinuclear structure, and [Mn 3 (salen) 3 (H 2 O)(CH 3 CN)Cr(CN) 5 (NO)] · 0.5CH 3 CN · 0.5MeOH · 2H 2 O ( 2 ) and [Mn(5‐Br‐salen)(H 2 O)(CH 3 OH)][Mn 2 (5‐Br‐salen) 2 (CH 3 OH)Cr(CN) 5 (NO)] · 2H 2 O ( 3 ) have novel 1D chain topological structures, whereas [{Mn(saltmen)} 4 Cr(CN) 5 (NO)]ClO 4 · 3H 2 O ( 4 ) displays a 2D layered network structure. Magnetic measurements show that the magnetic interaction between the Mn III and Cr I ions bridged by a cyanido group is antiferromagnetic for complexes 1 – 4 . The magnetic fitting for the trinuclear complex 1 gives the magnetic coupling constant J = –10.4(1) cm –1 and J′ = –1.29(2) cm –1 based on the isotropic Hamiltonian Ĥ = –2 JŜ Cr [ Ŝ Mn(1) + Ŝ Mn(2) ] – 2 J′Ŝ Mn(1) Ŝ Mn(2) . Complex 2 exhibits 3D antiferromagnetic ordering ( T N = 3.5 K) with a metamagnetic character below T N . Complex 3 exhibits an obvious frequency‐dependent AC magnetic susceptibility below 4.0 K, which is due to the spin‐glass behavior. The layered complex 4 displays 3D ferromagnetic ordering with T c = 6.4 K due to the ferromagnetic interaction between the ferrimagnetic layers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W1995751927 date "2007-03-01" @default.
- W1995751927 modified "2023-09-24" @default.
- W1995751927 title "Cyanido‐Bridged Dimetallic Complexes Derived from Manganese(III) Schiff Bases and Pentacyanidonitrosylchromate(I): Synthesis, Crystal Structure and Magnetic Properties" @default.
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- W1995751927 doi "https://doi.org/10.1002/ejic.200600958" @default.
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