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- W1995758612 abstract "Recent progress in the performance of soft x-ray monochromators has revealed new features in soft x-ray molecular photoabsorption spectra. We present here a comprehensive high resolution x-ray absorption study on the linear hydrocarbons C2H2n and C2D2n, adsorbed on Ag(100) and Cu(100) at 50 K and in the solid and the gas phase. A line shape analysis is given, for the bound as well as for the continuum resonances and the absorption thresholds, by means of models easily accessible to the experimentalist, leading to a quantitative understanding of the observed spectra, including the vibrational envelopes. Changes in intramolecular bond lengths upon core-hole excitation can be determined and tracked as a function of deuteration and chemisorption. The effects of the substrate bonding on the vibrational envelopes are analyzed." @default.
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- W1995758612 date "1992-01-15" @default.
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- W1995758612 title "High resolution x-ray absorption spectroscopy of linear hydrocarbons adsorbed on noble metal surfaces" @default.
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- W1995758612 doi "https://doi.org/10.1063/1.462140" @default.
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