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- W1995762364 abstract "Abstract The previously unknown linoleic acid peroxidation product 9,12‐dioxo‐10( Z )‐decenoic acid ( Z5 ) was detected in lentil seed fluor ( Lens culinaris Medik.) by electron impact mass spectrometry (El‐MS) after derivatization with pentafluorobenzyl‐hydroxylamine‐hydrochloride, methylation of acidic groups with diazomethane, and protection of hydroxylic groups with N ‐methyl‐ N ‐trimethylsilyl‐trifluoroacetamide. The structure of the natural product was confirmed by synthesis of Z5 , 9,12‐dioxo‐10( E )‐decenoic acid, and derivatives. EI‐MS, nuclear magnetic resonance and gas chromatographic data of these compounds and synthetic intermediates are discussed." @default.
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- W1995762364 date "2000-09-01" @default.
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- W1995762364 title "Synthesis of 9,12-Dioxo-10(Z)-dodecenoic acid, a new fatty acid metabolite derived from 9-hydroperoxy-10,12-octadecadienoic acid in lentil seed (Lens culinaris medik.)" @default.
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- W1995762364 doi "https://doi.org/10.1007/s11745-000-0605-z" @default.
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