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- W1995778247 abstract "The kinetics of the reaction [FeIII(edta)]–+[VIII(edta)]–⇌[FeII(edta)]2–+[VIVO(edta)]2–+ 2H+(edta = ethylenedinitrilotetra-acetate) have been studied at 25.0 °C in the forward direction at pH 5.4–7.1 and in the reverse direction at pH 2.5–4.0. Similar studies have been made on the corresponding system involving iron complexes with (trans- 1,2-cyclohexylenedinitrilo)tetra-acetate. Direct measurements of the equilibrium constants at pH 4.2–5.6 yielded values similar to those calculated from the kinetic results. The mechanism is believed to be of the inner-sphere type. At pH ⩽ 1 the reaction [FeIII(edta)]–+[VIII(edta)]–→ Fe2++ VIV+ H5edta+ occurs, the consumption of hydrogen ion and the form of vanadium(IV) depending on [H+]. The kinetics of this reaction show that as well as a bimolecular redox process, probably of the inner-sphere type, two other reaction paths occur. These involve the dissociation of one of the reactant complexes followed by a redox reaction between the cation so formed and the other edta complex." @default.
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- W1995778247 date "1983-01-01" @default.
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- W1995778247 title "Kinetics and equilibria in the redox reaction between ethylenedinitrilotetra-acetate complexes of iron(III) and vanadium(III) in aqueous solution" @default.
- W1995778247 doi "https://doi.org/10.1039/dt9830001449" @default.
- W1995778247 hasPublicationYear "1983" @default.
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