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- W1995800596 abstract "Condensation of adenosine with unsymmetrical ketones leads to 2′,3′-O-alkylidene acetals with a new chiral center. The diastereoisomers were separated chromatographically, and the ratio of products was found to be 3:1. The configuration of the new chiral centers was determined by nmr spectrosopy. The diastereoisomers were used as stereochemical probes for the active site of adenosine deaminase. By determination of the Km values it was shown that the binding of the S-diastereoisomers is strongly decreased in comparison with the R-compounds. The data imply a close proximity of the 2′,3′-site of the ribose moiety to the active site of adenosine deaminase." @default.
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- W1995800596 date "1981-03-01" @default.
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- W1995800596 title "R- and S-alkylidene acetals of adenosine: Stereochemical probes for the active site of adenosine deaminase" @default.
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- W1995800596 doi "https://doi.org/10.1016/0045-2068(81)90045-6" @default.
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