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- W1995807576 abstract "The interaction of trans-RuCl2(PMe3)4 with R2Mg, depending on the reaction conditions and the alkyl groups gives either (C2H4)Ru(PMe3)4 or cis-Ru(H)(C2H5)(PMe3)4 for R = ethyl, and cis-Ru(H)(nC3H7(PMe3)4 for R = n-propyl. The interaction of Et2Mg with trans-RuX2(dmpe)2 (X = Cl, CO2Me) gives either cis-Ru(Et2)dmpe)2 for X = Cl or trans-Ru(Et)2(dmpe)2 for X = CO2Me. NMR data for (C2H4)Ru(PMe3)4 suggest that ethylene is bound in the η2 or metallocyclopropane form, which is confirmed by a single-crystal X-ray diffraction study. This shows a relatively long carbon-carbon bond distance of 1.44(1)Å between the “ethylene” carbons. The structure of cis-Ru(H)(C2H5)(PMe3)4 has also been confirmed by a single-crystal X-ray diffraction study. Possible mechanisms for the observed reactivities are considered." @default.
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- W1995807576 date "1984-01-01" @default.
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- W1995807576 title "Alkyl, hydrido and related compounds of ruthenium with trimethylphosphine and bis(1,2-dimethylphosphino)ethane. X-ray crystal structures of cis-hydridoethyltetrakis(trimethylphosphine)-ruthenium(II) and ethylene tetrakis-(trimethylphosphine)ruthenium(0)" @default.
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- W1995807576 doi "https://doi.org/10.1016/s0277-5387(00)84672-0" @default.
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