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• W1995807712 abstract "Abstract Complexes [Cu(en) 2 MnCl 4 ] · Solv [en = ethylenediamine, Solv = DMF ( 1 ), DMSO ( 2 )], [Cu(phen) 2 Cl] 2 [MnCl 4 ] · DMF ( 3 ) and [Cu(phen) 2 Cl] 2 [Mn(phen)Cl 3 ]Cl · 2H 2 O ( 4 ) [phen = 1,10-phenanthroline] have been synthesized by the interaction of copper metal with MnO 4 - in DMF, DMSO or CH 3 OH solutions of ethylenediamine or 1,10-phenanthroline. X-ray crystallographic studies of 1 and 2 have shown that the complexes included [Cu(en) 2 ] 2+ and [MnCl 4 ] 2− building blocks forming zigzag chains, which originate from H-bonding of DMF or DMSO guest molecules. In the crystal structures of 3 – 4 , [Cu(phen) 2 Cl] + cations and [MnCl 4 ] 2− ( 3 ) or [Mn(phen)Cl 3 ] − (4) anions form 3D supramolecular frameworks through π–π stacking interactions between phen surfaces, C–H···Cl interactions and H-bonding supported by the solvent molecules. The EPR spectra of the polycrystalline compounds 1 – 3 are different as compared to spectrum for 4 due to the dominant effect of Mn(II) coordination geometry; tetrahedral in the former compounds and square pyramidal in the latter. The hyperfine splitting of frozen solution spectra indicates separation of the Mn(II) and Cu (en) 2 2 + centers under the solvents influence." @default.
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• W1995807712 date "2009-03-01" @default.
• W1995807712 modified "2023-09-23" @default.
• W1995807712 title "as a source of manganese in the direct synthesis of heterobimetallic Cu/Mn complexes" @default.
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• W1995807712 doi "https://doi.org/10.1016/j.ica.2008.06.021" @default.
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