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• W1995909559 abstract "Three new homo- and heterometallic hexanuclear complexes [Mn2MII4O2(PhCOO)10(DMF)4] (with M = Mn (1), Co (2) or Ni (3) and DMF = dimethylformamide) have been synthesized by redox generation of benzoate ligands from benzaldehyde in a one-pot reaction. All of the compounds are isostructural and crystallize in the I-42d space group of the tetragonal system, data for 1: a = 27.2249(8) Å, c = 25.5182(5) Å, R1 = 0.0681. The crystal structure contains isolated molecules. Each molecule consists of 2 × MnIII surrounded by four MII ions to form two edge-sharing OMn2M2 tetrahedra giving rise to the [Mn2M4O2] core. The coordination sphere of each metal is completed by the bridging benzoate ligands and DMF molecules. The magnetic susceptibilities of 1−3 have been measured in the 1.8 K < T < 300 K temperature range. The magnetic susceptibilities for 1 and 2 pass through a broad maximum at low temperature which is characteristic of the diamagnetic ground state, while for 3 no maximum is detected down to 1.8 K. The magnetic data have been interpreted quantitatively for 1 and 3 on the basis of spin exchange interactions between the metallic centers (spin Hamiltonian for a pair being HAB = −JAB SA·SB). Single-crystal measurements on [Mn6O2(PhCOO)10(CH3CN)4] (4) show that significant magnetic anisotropy develops at low temperature." @default.
• W1995909559 created "2016-06-24" @default.
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• W1995909559 date "2005-07-02" @default.
• W1995909559 modified "2023-10-18" @default.
• W1995909559 title "Synthesis, Structure, and Magnetism of Heterometallic Carboxylate Complexes [Mn^III₂M^II₄O₂(PhCOO)₁₀(DMF)₄], M = Mn^II, Co^II, Ni^II" @default.
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• W1995909559 doi "https://doi.org/10.1021/ic0505448" @default.
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