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• W1995934021 abstract "Adsorption of phenol and nonylphenol from aqueous solutions on microporous activated carbons has been studied. The phenol isotherm changes from L-shaped for surface oxygen group free carbon (I sample) to a two-stepped isotherm for oxidized carbon (IN sample, HNO3 treated) Furthermore, the adsorbed amounts diminish in about 25% on IN carbon. It is proposed that a change in the adsorption mechanism take place; i.e., weak interaction forces between the π electrons in phenol and the π electron in carbon are present on the original I carbon, while a donor–acceptor complex on the oxidized IN carbon is operating between basic surface oxygen groups and phenol aromatic rings. The shape of nonylphenol isotherms is two-stepped for both carbons. The introduction of acidic oxygen surface groups on the carbon enhances the specific nonylphenol adsorption by about 40%. This may be interpreted as being due to the fact that nonylphenol is hydrogen-bonded to the oxidized carbon surface by means of acidic groups. Thermal desorption experiments indicate that phenol is mainly physisorbed. Thermal desorption further confirms that nonylphenol is possibly bonded to oxygen surface groups by hydrogen bonds." @default.
• W1995934021 created "2016-06-24" @default.
• W1995934021 creator A5015834826 @default.
• W1995934021 creator A5039920152 @default.
• W1995934021 date "2001-02-01" @default.
• W1995934021 modified "2023-10-14" @default.
• W1995934021 title "Comparative Study of the Adsorption from Aqueous Solutions and the Desorption of Phenol and Nonylphenol Substrates on Activated Carbons" @default.
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• W1995934021 doi "https://doi.org/10.1006/jcis.2000.7300" @default.
• W1995934021 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11161516" @default.
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