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- W1995939102 abstract "Crystals of bis[bis(diisopropylamino)phosphanyl]diazomethane P2N6C25H56, M = 502.7 belong to the monoclinic space group, C2/c with a 12.044(2), b 28.661(4) c 10.301(1) Å, β 116.13(1)°, V 3192(2) Å3 and Z = 4. The structure was refined by use of 1275 non zero Mo-Ka reflections to R = 0.052 at 293 K. The unit cell contains discrete monomeric molecules. The structural parameters of the CN2 group are very close to those found for other diazoalkanes. The linear diazo group C(1)N(1)N(2) lies on the crystallographic two fold axis of the unit cell. The ability of bis[bis(diisopropylamino)phosphanyl]diazomethane to act as a chelating or reducing agent is discussed." @default.
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- W1995939102 date "1989-08-01" @default.
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- W1995939102 title "First structural characterization of an α-diazophosphane: crystal structure of bis[bis(diisopropylamino)phosphanyl]diazomethane [(i-Pr2N)2P]2CN2" @default.
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- W1995939102 doi "https://doi.org/10.1016/0022-328x(89)87094-9" @default.
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