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• W1995940903 abstract "Salvinorin A (1) is a hallucinogenic neoclerodane diterpene isolated from the widely available psychoactive plant Salvia divinorum and is the first example of a non-nitrogenous opioid receptor ligand. At present, there is little information available as to why this compound is selective for kappa opioid receptors. One approach to better understanding the mode of binding of 1 at kappa receptors is to systematically alter the structure of 1 and examine the effects on opioid receptor affinity and activity. Currently, there is a paucity of methods described for the preparation of analogues derived from 1. Here, we report the investigation of several chemical transformations of 1 isolated from S. divinorum. In particular, this work provides a semisynthesis of salvinicins A (2) and B (3) and has identified 10a as the first neoclerodane diterpene with delta opioid antagonist activity." @default.
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• W1995940903 date "2005-12-22" @default.
• W1995940903 modified "2023-10-09" @default.
• W1995940903 title "Synthetic Studies of Neoclerodane Diterpenes from <i>Salvia </i><i>d</i><i>ivinorum</i>: Semisynthesis of Salvinicins A and B and Other Chemical Transformations of Salvinorin A" @default.
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• W1995940903 doi "https://doi.org/10.1021/np050398i" @default.
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