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- W1995999749 abstract "The chemical and electrochemical reduction of the niobocene dichlorides [Nb(η5-C5H4SiMe3)2Cl2]1, [Nb(η5-C5Me5)2Cl2] 2 and [Nb(η5-C5Me4Et)2Cl2] 3, in the presence of carbon dioxide has been investigated. Formation of compounds of the type [Cp2Nb(CO2)] and [Cp2(∗)NbCl(CO2))] 1 has been established by means of IR, ESR and/or NMR spectroscopy. They contain a labile η2-CO2. The order of stability increases with the degree of substitution the Cp. Less stable intermediates in the reduction of the system [Cp2NbCl2]/CO2 are discussed on the basis of cyclovoltammetric and coulometric data." @default.
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- W1995999749 date "1995-08-01" @default.
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- W1995999749 title "Electrochemical and chemical reduction of niobocene dichlorides in the presence of carbon dioxide" @default.
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- W1995999749 doi "https://doi.org/10.1016/0022-328x(95)05526-u" @default.
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