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- W1996001686 abstract "The result of Noyes et al. that cis or trans di-iodoethylene will rapidly exchange I atoms with I2* via an I-atom addition to the double bond (relative to much slower geometrical isomerization) is shown to be compatible with a planar structure for the intermediate free radical. A tetrahedral structure for the free-radical end would lead to nearly equivalent rates of exchange and isomerization. The recent suggestion by Skell et al. that the stable form of the β-iodo-alkyl radical is I bridged is shown to be incorrect. His observations are explained in terms of the I atom catalyzed, concerted addition of I2 to the olefin." @default.
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- W1996001686 date "1965-06-15" @default.
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- W1996001686 title "Kinetic Evidence Concerning the Geometry of Substituted Methyl Radicals" @default.
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