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- W1996010044 abstract "Die Komplexe M(CO)4L2 (M Cr, Mo, W; L Me2PSMe, Me2PSeMe, (CF3)2PSMe, (CF3)2PSeMe) werden durch Umsetzung der Norbornadienverbindungen M(CO)4NBD mit L bei Raumtemperatur bzw. bei 35°C dargestellt. Die primar gebildeten cis-Komplexe lagern sich bei erhohter Temperature in die trans-Isomeren um. Die neuen Verbindungen werden analytisch und spektrometrisch (IR, NMR, MS) charakterisiert.Perfluoromethyl Element Ligands. XXIX. Preparation and Spectroscopic Investigation of M(CO)4L2 Complexes (M Cr, Mo, W; L Me2PSMe, Me2PSeMe, (CF3)2PSMe, (CF3)2PSMe)The complexes M(CO)4L2 (see Inhaltsubersicht) have been prepared by the reaction of tetracarbonyl norbornadiene metal compounds M(CO)4NBD with L at room temperature or 35°C, respectively. The cis-complexes formed in the first step undergo rearrangement to trans-isomers at higher temperatures. New compounds have been characterized by analytical and spectroscopic (IR, NMR, MS) methods." @default.
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- W1996010044 date "1984-12-01" @default.
- W1996010044 modified "2023-09-26" @default.
- W1996010044 title "Perfluormethyl-Element-Liganden. XXIX. Darstellung und spektroskopische Untersuchungen von M(CO)4L2-Komplexen (M = Cr, Mo, W; L = Me2PSMe, Me2PSeMe, (CF3)2PSMe, (CF3)2PSeMe)" @default.
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- W1996010044 doi "https://doi.org/10.1002/zaac.19845191207" @default.
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