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- W1996051779 abstract "Abstract The reactions of N 2 O and CH 4 have been studied on calcium hydroxyapatite with various stoichiometries at 973 and 1023 K, partial pressures of CH 4 , 28.7 kPa and of N 2 O, 4.1 and 12.3 kPa, 30 ml min −1 and catalyst masses of 0.25, 0.5 and 0.75 g. On CaHAp with Ca/P from 1.59 to 1.72 the conversion of N 2 O was 80±5% while that of CH 4 was 4±1%, regardless of Ca/P. The introduction of tetrachloromethane (TCM), with partial pressures: 0.085, 0.17 and 0.34 kPa, to the feedstream resulted in decreases in the conversions of both N 2 O and CH 4 and increases in the selectivities to C 2 hydrocarbons and CO, apparently due to the formation of chlorapatite and/or nonstructural chlorine species in the catalysts." @default.
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- W1996051779 date "1999-07-05" @default.
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- W1996051779 title "Oxidation of methane with nitrous oxide on calcium hydroxyapatites in the presence and absence of tetrachloromethane" @default.
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