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- W1996069618 abstract "Undoped BaTiO3 perovskite oxide is more effective than SrTiO3 and La2Ti2O7 oxide as anode catalyst in SOFC fueled with H2S-containing methane. Electrochemical performance, impedance spectroscopy and other characterizations show that pure BaTiO3 is a good anode catalyst for conversion of methane in SOFC, especially in H2S-containing atmospheres. Compared with SrTiO3 and La2Ti2O7 samples, the BaTiO3−based fuel cell has higher resistance to carbon deposition, better electrochemical performance and much higher stability during long term operation. A maximum power density of 135 mW cm−2 was achieved at 900 °C with 0.5% H2S–CH4 in a fuel cell having a 300 μm thick YSZ electrolyte. High catalytic activity for methane conversion, mixed electronic and ionic conductivity, and the surface basicity of BaTiO3 unexpectedly provides promising performance as anodes in SOFC." @default.
- W1996069618 created "2016-06-24" @default.
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- W1996069618 date "2012-09-01" @default.
- W1996069618 modified "2023-10-07" @default.
- W1996069618 title "Application of BaTiO3 as anode materials for H2S-containing CH4 fueled solid oxide fuel cells" @default.
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- W1996069618 doi "https://doi.org/10.1016/j.jpowsour.2012.03.106" @default.
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