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- W1996074446 abstract "The molecule Fe2(CO)7(PhC2Ph)2 has been studied by 13C NMR and is static at −40°C with a spectrum which is consistent with the known structure observed in the crystals. In the range −40 to +41°C the three carbonyl resonance coalesce possibly by a single carbonyl averaging process. At room temperature violet Fe3(CO)8(PhC2Ph)2 is found to be static by 13C NMR having a spectrum consistent with the known solid state structure. Dark green Fe3(CO)8(PhC2Ph)2 is static via 13C NMR at −62°C with a spectrum consistent with the known solid state structure. Between −62 and +96°C a fluxional process occurs which scrambles the bridge carbonyls and four of the six terminal carbonyl groups. In this process the bridging carbonyls appear to be preferentially moving toward the iron atoms with which they have the shortest iron-carbon bond as observed in the solid state structure." @default.
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- W1996074446 date "1975-10-01" @default.
- W1996074446 modified "2023-09-23" @default.
- W1996074446 title "A 13C NMR study of some derivatives obtained from iron carbonyls and diphenylacetylene" @default.
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