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- W1996076364 abstract "The local structure of the solvated lithium cation in ethylene carbonate (EC) solutions has been investigated using Raman spectroscopy. The relative intensity change of the split Raman line at ∼ 900 cm−1 in LiClO4/EC was treated quantitatively. This splitting originates from the coexistence of two type EC molecules; one solvates to Li cation and the other does not solvate to Li cation. The resultant intensity data have been applied to the analysis of the Li+-EC solution. The possibilities of the determination of the degree of dissociation of LiClO4 and that of the solvation number of Li+ in a contact ion pair were also discussed. It was found that this Raman line is useful for analysing the solution structure in Li+-EC systems. Basic intensity parameters for such analyses can be determined." @default.
- W1996076364 created "2016-06-24" @default.
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- W1996076364 date "1989-11-01" @default.
- W1996076364 modified "2023-10-18" @default.
- W1996076364 title "Raman intensity study of local structure in non-aqueous electrolyte solutions—I. Cation-solvent interaction in LiClO4/ethylene carbonate" @default.
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- W1996076364 doi "https://doi.org/10.1016/0013-4686(89)87040-9" @default.
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