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• W1996129417 abstract "The molecular crystal of tin tetraiodide is known to exhibit unusual features under pressure, such as solid-state amorphization. The low-pressure crystalline phase has a melting curve with a maximum at about 1.5 GPa, dividing the liquid phase into two states with different structures. However, the thermodynamic properties of this solid phase are still unknown. For proper thermodynamic measurements for the solid phase, we present here the Parsafar-Mason and Birch-Murnaghan-Anderson equations of state for the phase as a predecessor. The validity of the equations was confirmed by recent experimental observations. As far as can be seen from the equations of state, no remarkable anharmonic properties are expected, in the sense that the thermal pressure is well described by a linear function of temperature, i.e., $ensuremath{alpha}{K}_{T}$ (where $ensuremath{alpha}$ and ${K}_{T}$ are the coefficient of thermal expansion and the isothermal bulk modulus, respectively) is virtually independent of temperature. In addition to the equations of state, we also report a unique means of holding a chemically active sample, which we established through the in situ x-ray diffraction measurements for SnI${}_{4}$ at high pressures and temperatures." @default.
• W1996129417 created "2016-06-24" @default.
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• W1996129417 date "2011-10-07" @default.
• W1996129417 modified "2023-10-18" @default.
• W1996129417 title "Equation of state for the low-pressure crystalline phase of SnI4" @default.
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• W1996129417 doi "https://doi.org/10.1103/physrevb.84.144105" @default.
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