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- W1996132695 abstract "The first infrared spectra of protonated hydrogen clusters in the gas phase have been observed. Predissociation spectra were taken with a tandem mass spectrometer: mass selected hydrogen cluster ions were irradiated inside a rf ion trap by a tunable infrared laser, and the fragment ions created by photodissociation of the clusters were mass selected and detected. Spectra for each product channel were measured by counting fragment ions as a function of laser frequency. Low resolution spectra (Δν=10 cm−1) in the region from 3800 to 4200 cm−1 were observed for the ions H+5, H+7, and H+9 at 3910, 3980, and 4020 cm−1, respectively. A band was also observed for H+5 at 3532 cm−1. No rotational structure was resolved. The frequencies of the band maxima agree well with the frequencies predicted by previous ab initio calculations for the highest modes." @default.
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- W1996132695 date "1985-10-01" @default.
- W1996132695 modified "2023-10-09" @default.
- W1996132695 title "The vibrational predissociation spectroscopy of hydrogen cluster ions" @default.
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- W1996132695 doi "https://doi.org/10.1063/1.449127" @default.
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