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- W1996143154 abstract "Ein Teil des Phasendiagramms Pd-S wurde verbessert und ein Teil des Phasendiagramms Pd-Cu-S wurde ausgearbeitet. Die Phase Pd16S7 hat eine kubisch innenzentrierte Struktur mit 46 Atomen in der kubischen Zelle, die verwandt zur γ-Messing Struktur ist. Die Phasen Pd4S, Pd3S.h, Pd16S7, PdS und PdS2 lassen sich mit dem Zweikorrelationenmodell als energetisch vorteilhaft erkennen. Daher ist dieses Modell auch bei messingartigen Legierungen mit elektronenreichen B-Komponenten sinnvoll. Part of the phase diagram for the system Pd-S has been amended and part of the Pd-Cu-S diagram determined. The phase Pd16S7 has a cubic body-centred structure with 46 atoms in the cubic cell, and is related to the γ-brass structure. The phases Pd4S, Pd3S.h, Pd16S7, PdS and PdS2 may be interpreted as energetically favourable in terms of the two-electron correlation model. Thus this model is also compatible with experimental results for brass-like structures with electron-rich B components." @default.
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- W1996143154 date "1976-12-01" @default.
- W1996143154 modified "2023-09-25" @default.
- W1996143154 title "Kristallstruktur von Pd16S7" @default.
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- W1996143154 doi "https://doi.org/10.1016/0022-5088(76)90157-0" @default.
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