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- W1996179968 abstract "A new method for the regioselective preparation of silyl enol ethers from acyloin derivatives using silyllithium reagents has been developed. Both dimethylphenyl- and methyldiphenylsilyllithium were found to be effective, the latter providing greater stereocontrol. The reaction is believed to proceed via Brook rearrangement assisted by expulsion of the adjacent leaving group. A number of acyclic acyloin derivatives were reacted to form the corresponding silyl enol ethers in good to excellent yield." @default.
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- W1996179968 date "2008-03-01" @default.
- W1996179968 modified "2023-09-28" @default.
- W1996179968 title "Preparation of silyl enol ethers from acyloin derivatives using silyllithium reagents" @default.
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- W1996179968 doi "https://doi.org/10.1016/j.tetlet.2008.01.133" @default.
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