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- W1996180074 abstract "A kinetic study was conducted to ascertain whether heat transfer controls the rate of hydrogen evolution from LaNi5H6. A series of LaNi5H6-Al mixtures containing 2.5, 5, 10, 20, 30 and 100 wt.% LaNi5H6 were prepared and the hydrogen desorption rates were measured. It was found that in mixtures containing 100, 30, 20, 10 and 5 wt.% LaNi5H5 the desorption rates increased with increasing percentage of aluminum. This indicates that heat transfer is rate controlling. Desorption rates from mixtures containing 5 and 2.5 wt.% LaNi5H6, however, were almost the same indicating that in very dilute mixtures the heat transfer rate is sufficient to achieve near-isothermal conditions. The reaction was found to be first order for each mixture under isobaric conditions." @default.
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- W1996180074 date "1983-05-01" @default.
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- W1996180074 title "The effect of heat transfer on the desorption kinetics of LaNi5H6" @default.
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- W1996180074 doi "https://doi.org/10.1016/0022-5088(83)90103-0" @default.
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