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- W1996202264 abstract "A detailed solution of the fine-structure splitting of the ground state of the chromium ion is given. This solution assumes an electric field of cubic symmetry with a small trigonal distortion and the residual spin-orbit coupling superposed. The effect of a magnetic field at an arbitrary orientation is calculated.Absorption positions and relative intensities are calculated and checked with experiment. Lines of character predominantly $ensuremath{Delta}{S}_{z}=2, 3$ are shown to have sufficient $ensuremath{Delta}{S}_{z}=1$ character to give the experimentally determined intensities. So-called forbidden transitions are accounted for quantitatively by this detailed calculation. Shapes of absorption peaks are Lorentzian for dilute specimens and Gaussian for full-strength alum. A small variation of trigonal Stark field from one paramagnetic ion to another is sufficient to account for the observed line width." @default.
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- W1996202264 date "1957-01-15" @default.
- W1996202264 modified "2023-09-29" @default.
- W1996202264 title "Paramagnetic Resonance Spectrum of Ammonium Chromium Alum" @default.
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- W1996202264 doi "https://doi.org/10.1103/physrev.105.447" @default.
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