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• W1996202833 abstract "A new synthetic strategy has been developed for the formation of densely packed monolayers on oxide surfaces. This technique involves a simple two-step procedure in which the oxide surface is initially chlorinated and then exposed to alcohol molecules for monolayer formation via Si−O linkages. We demonstrate this approach with the formation of octadecanol (C18) monolayers on the oxide-terminated Si(111) surface. Characterization of the resulting C18H37O− monolayer by a combination of techniques reveals a densely packed film with partial disorder. At the highest surface coverage, the thickness of the film is determined to be 24 Å. Kinetics of monolayer growth is characterized by a fast initial step at low coverage; the rate constant decreases by 3 orders of magnitude when surface coverage approaches saturation." @default.
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• W1996202833 date "2001-08-11" @default.
• W1996202833 modified "2023-09-24" @default.
• W1996202833 title "Two-Step Approach to the Formation of Organic Monolayers on the Silicon Oxide Surface" @default.
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• W1996202833 doi "https://doi.org/10.1021/la010821x" @default.
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