FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1996207112> ?p ?o ?g. }

• W1996207112 endingPage "22" @default.
• W1996207112 startingPage "14" @default.
• W1996207112 abstract "The chlorodisilanes SiClMe2SiClMe2 (1), SiCl2MeSiCl2Me (2), SiCl3SiCl3 (3) and a 9:1 mixture of 2 and SiCl3SiCl2Me (4) were reacted with the electron-rich alkene tetrakis-(dimethylamino)-ethylene (TDAE) in n-hexane as well as in polar solvents. While 1 gave no reaction at all, 3 underwent a disproportionation reaction into SiCl4 and Si(SiCl3)4. Also 2 and mixtures of 2 and 4 were disproportionated into MeSiCl3 (2a) and methylchlorooligosilanes. Additionally a crystalline mixture of Si3Me3Cl6·TDAE (5a) plus Si3Me2Cl7·TDAE (5b) was obtained by reaction of a 9:1 mixture of 2 and 4 with TDAE in n-hexane as well as in 1,2-dimethoxyethane. The reaction of 2 with TDAE in acetonitrile (MeCN) led to a crystalline precipitation of [TDAE]Cl2·MeCN (6·MeCN) in addition to MeSiCl3 and methylchlorooligosilanes. The structures of 5b and 6·MeCN were determined by X-ray crystallography beside their NMR and IR spectroscopic characterization. Compound 5b crystallizes in the monoclinic space group P2/c (Z=4), 6·MeCN in the orthorhombic space group Pna21 (Z=4). The structure of 5b reveals a [TDAE]+ radical cation and a 1,2-Me2Si3Cl7− anion with a pentacoordinated central silicon atom." @default.
• W1996207112 created "2016-06-24" @default.
• W1996207112 creator A5008660647 @default.
• W1996207112 creator A5039877065 @default.
• W1996207112 creator A5048481954 @default.
• W1996207112 creator A5057021505 @default.
• W1996207112 creator A5060904103 @default.
• W1996207112 creator A5065878297 @default.
• W1996207112 date "2002-11-01" @default.
• W1996207112 modified "2023-10-03" @default.
• W1996207112 title "Interactions of chloromethyldisilanes with tetrakis(dimethylamino)ethylene (TDAE), formation of [TDAE]+ [Si3Me2Cl7]−" @default.
• W1996207112 cites W1965652176 @default.
• W1996207112 cites W1991544298 @default.
• W1996207112 cites W1993165197 @default.
• W1996207112 cites W2003232396 @default.
• W1996207112 cites W2005866854 @default.
• W1996207112 cites W2009701796 @default.
• W1996207112 cites W2009740575 @default.
• W1996207112 cites W2014610702 @default.
• W1996207112 cites W2017617586 @default.
• W1996207112 cites W2025671500 @default.
• W1996207112 cites W2029148158 @default.
• W1996207112 cites W2033206792 @default.
• W1996207112 cites W2034410062 @default.
• W1996207112 cites W2036428180 @default.
• W1996207112 cites W2047201202 @default.
• W1996207112 cites W2079805079 @default.
• W1996207112 cites W2081260421 @default.
• W1996207112 cites W2095993238 @default.
• W1996207112 cites W2109934711 @default.
• W1996207112 cites W2113674183 @default.
• W1996207112 cites W2146848389 @default.
• W1996207112 cites W2158846638 @default.
• W1996207112 cites W2319229291 @default.
• W1996207112 cites W2324775570 @default.
• W1996207112 cites W2326309901 @default.
• W1996207112 cites W2329028083 @default.
• W1996207112 cites W2332401636 @default.
• W1996207112 cites W2951135365 @default.
• W1996207112 doi "https://doi.org/10.1016/s0022-328x(02)01856-9" @default.
• W1996207112 hasPublicationYear "2002" @default.
• W1996207112 type Work @default.
• W1996207112 sameAs 1996207112 @default.
• W1996207112 citedByCount "27" @default.
• W1996207112 countsByYear W19962071122013 @default.
• W1996207112 countsByYear W19962071122014 @default.
• W1996207112 countsByYear W19962071122016 @default.
• W1996207112 countsByYear W19962071122017 @default.
• W1996207112 countsByYear W19962071122019 @default.
• W1996207112 countsByYear W19962071122022 @default.
• W1996207112 crossrefType "journal-article" @default.
• W1996207112 hasAuthorship W1996207112A5008660647 @default.
• W1996207112 hasAuthorship W1996207112A5039877065 @default.
• W1996207112 hasAuthorship W1996207112A5048481954 @default.
• W1996207112 hasAuthorship W1996207112A5057021505 @default.
• W1996207112 hasAuthorship W1996207112A5060904103 @default.
• W1996207112 hasAuthorship W1996207112A5065878297 @default.
• W1996207112 hasConcept C115624301 @default.
• W1996207112 hasConcept C147789679 @default.
• W1996207112 hasConcept C155647269 @default.
• W1996207112 hasConcept C161790260 @default.
• W1996207112 hasConcept C17365422 @default.
• W1996207112 hasConcept C17525397 @default.
• W1996207112 hasConcept C178790620 @default.
• W1996207112 hasConcept C185592680 @default.
• W1996207112 hasConcept C2777463227 @default.
• W1996207112 hasConcept C2778597550 @default.
• W1996207112 hasConcept C2778734912 @default.
• W1996207112 hasConcept C2778969155 @default.
• W1996207112 hasConcept C61276311 @default.
• W1996207112 hasConcept C68801617 @default.
• W1996207112 hasConcept C8010536 @default.
• W1996207112 hasConceptScore W1996207112C115624301 @default.
• W1996207112 hasConceptScore W1996207112C147789679 @default.
• W1996207112 hasConceptScore W1996207112C155647269 @default.
• W1996207112 hasConceptScore W1996207112C161790260 @default.
• W1996207112 hasConceptScore W1996207112C17365422 @default.
• W1996207112 hasConceptScore W1996207112C17525397 @default.
• W1996207112 hasConceptScore W1996207112C178790620 @default.
• W1996207112 hasConceptScore W1996207112C185592680 @default.
• W1996207112 hasConceptScore W1996207112C2777463227 @default.
• W1996207112 hasConceptScore W1996207112C2778597550 @default.
• W1996207112 hasConceptScore W1996207112C2778734912 @default.
• W1996207112 hasConceptScore W1996207112C2778969155 @default.
• W1996207112 hasConceptScore W1996207112C61276311 @default.
• W1996207112 hasConceptScore W1996207112C68801617 @default.
• W1996207112 hasConceptScore W1996207112C8010536 @default.
• W1996207112 hasIssue "1-2" @default.
• W1996207112 hasLocation W19962071121 @default.
• W1996207112 hasOpenAccess W1996207112 @default.
• W1996207112 hasPrimaryLocation W19962071121 @default.
• W1996207112 hasRelatedWork W1031340909 @default.
• W1996207112 hasRelatedWork W150661128 @default.
• W1996207112 hasRelatedWork W1979358532 @default.
• W1996207112 hasRelatedWork W2030390379 @default.
• W1996207112 hasRelatedWork W2082823139 @default.
• W1996207112 hasRelatedWork W2104742556 @default.
• W1996207112 hasRelatedWork W2262641225 @default.

• next