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- W1996210821 abstract "The mass spectra of a group of m- and p-substituted acetanilides were measured to determine the effect of the substituents, if any, on the rate of C2H2O expulsion (rearrangement) vs. the rate of [CH3CO]+ formation (simple cleavage). Our results agree with observations of others in that substituents which raise the ionization potential of the aromatic ring appear to localize, on the average, less charge density on this locus, and conversely. The atomic composition of the substituent, however, irrespective of its position, seems to determine the relative rates of the competing reaction. Although in several cases Zm/Zp values were close to unity, rearrangement of isomeric molecular ions to a common species is shown not to occur." @default.
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- W1996210821 title "Substituent effects in the fragmentation reactions of acetanilides and phenyl acetates" @default.
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- W1996210821 doi "https://doi.org/10.1002/oms.1210020604" @default.
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