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- W1996236134 abstract "The photophysical properties of a series of Ru(II) complexes containing benzo[i]dipyrido[3,2-a:2',3'-c]phenazine (dppn) as a ligand are reported. Transient absorption spectroscopy studies indicate that, in contrast to related Ru(dppz) complexes (dppz = dipyrido[3,2-a:2',3'-c]phenazine), the excited state of all the dppn systems is a long-lived pipi* triplet state. Computational studies (DFT and TD-DFT) confirm that the excited state is based on the dppn ligand. Near-infrared luminescence studies reveal that the complexes are efficient singlet oxygen sensitizers with yields of 70-83%." @default.
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- W1996236134 date "2009-09-30" @default.
- W1996236134 modified "2023-10-01" @default.
- W1996236134 title "Photophysical Properties and Singlet Oxygen Production by Ruthenium(II) Complexes of Benzo[<i>i</i>]dipyrido[3,2-<i>a</i>:2′,3′-<i>c</i>]phenazine: Spectroscopic and TD-DFT Study" @default.
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- W1996236134 doi "https://doi.org/10.1021/jp906716g" @default.
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