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- W1996242361 abstract "We report the observation of the resolved fine structure of Gd3+ in single crystals of Pd. Analysis in terms of the classical theory for the Gd3+ ion in a cubic crystal field1 permits us to deduce the crystal field parameter, b4, to be + 29 ± 2 G. Anomalous temperature dependence of the spectrum of the highest concentration of Gd sample leads us to believe that exchange narrowing processes such as those found recently for Gd in Au2 may be operative. A discrepancy exists between the values obtained for the exchange constant between the localised moment and conduction electrons deduced from measurements of the local moment g-shift and temperature dependence of the resonance linewidth. La structure fine du Gd3+ dans des monocristaux de Pd a été observée. Une analyse selon la théorie classique de l'ion Gd3+ dans un champ cristallin cubique1 conduit à un parametre de champ cristallin b4 de 29 ± 2 G. Une dépendance anormale du spectre de l'échantillon le plus concentré en Gd en fonction de la température suggère que des processus de rétrecissement par échange analogues à ceux rencontrés récemment pour le Gd dans l'Au2 sont à prendre en considération. Il y a un désaccord entre les valeurs de la constante d'échange entre le moment localisé et les électrons de conduction déduites de la mesure du ‘g-shift’ de l'ion localisé et de la dépendance en température de la largeur de raie." @default.
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- W1996242361 date "1972-08-01" @default.
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- W1996242361 title "The paramagnetic resonance of Gd in single crystals of Pd" @default.
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- W1996242361 doi "https://doi.org/10.1016/0038-1098(72)90117-2" @default.
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