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- W1996253276 abstract "We tested the dielectric friction theory of the viscosity B coefficient for the ion in solutions which was derived using the Hubbard–Onsager electrohydrodynamic equation. The temperature dependence of the B values for some monovalent ions in water, methanol, formamide, and N-methylacetamide was examined using the literature values. The theory predicts that there is almost no temperature dependence of B. However, most of the observed B values in the nonaqueous solvents decrease with increasing temperature. The B values for medium-sized ions (such as I−) in water increase with increasing temperature. These observations cannot be explained by the theory. This result lends support to the popular idea that the sign of the temperature coefficient of B can be used as a measure of the structural effect of the ion in water. The parallelism between electrolyte viscosity and conductance is also discussed." @default.
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- W1996253276 date "1988-10-15" @default.
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- W1996253276 title "The effect of dielectric friction on the viscosity <i>B</i> coefficient for electrolytes. Temperature dependence" @default.
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- W1996253276 doi "https://doi.org/10.1063/1.455645" @default.
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