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• W1996253458 abstract "Intermolecular cycloadditions of five-membered cyclic carbonyl ylides 3 with indole, N-methylindole and N-benzylindole afforded decahydrobenzo[c]carbazole 4a–f or decahydrocyclopenta[c]carbazole 4g–h derivatives with high regioselectivity. With N-benzoylindole and N-sulphonylindole, decahydrobenzo[c]carbazoles 4i,j and the regioisomer decahydrobenzo[a]carbazoles 5i,j are isolated. The electron withdrawing substituent reduces both regioselectivity and reactivity of the cycloadditions. This methodology generated oxa-bridged (unnatural) decahydrobenzocarbazole derivatives with complete control of four stereocenters." @default.
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• W1996253458 date "2001-01-01" @default.
• W1996253458 modified "2023-10-09" @default.
• W1996253458 title "Novel regioselective synthesis of decahydrobenzocarbazoles using rhodium generated carbonyl ylides with indoles" @default.
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• W1996253458 doi "https://doi.org/10.1016/s0040-4039(00)01990-0" @default.
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