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• W1996261119 endingPage "3397" @default.
• W1996261119 startingPage "3391" @default.
• W1996261119 abstract "The triplet−triplet fluorescence and fluorescence excitation spectra of two new, planar diaryl carbenes in n-hexane and n-heptane were studied at cryogenic temperatures. Fluorescence decays were fitted to three exponential functions. Fluorescence decays of 12-oxo-5(12H)-naphthacenylidene were sensitive to the presence of a magnetic field, and this dependence allowed the estimation of the zero field splitting parameters (D) of the excited triplet state of this compound, which were 0.037 ± 0.010 and 0.03 ± 0.015 cm-1 for the low- and high-energy sites, respectively. These results are corroborated by computational studies of the ground-state preferences and the triplet excitation energies." @default.
• W1996261119 created "2016-06-24" @default.
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• W1996261119 date "2000-03-28" @default.
• W1996261119 modified "2023-10-16" @default.
• W1996261119 title "Spectroscopic Studies of 12-Oxo-5(12<i>H</i>)-naphthacenylidene and 7<i>H</i>-Benz[<i>d</i><i>e</i>]anthracen-7-ylidene in Shpolskii Matrixes at 5 K" @default.
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• W1996261119 doi "https://doi.org/10.1021/jp994183r" @default.
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