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- W1996308504 abstract "Rate constants for the reactions of acrylonitrile, methacrylonitrile, methyl and ethyl acrylate with O3 have been determined with the help of a flow system coupled to an u.v. spectrophotometer. The rate constants obtained have enabled an estimation of the tropospheric lifetimes with respect to O3 and have also offered a clue to the nature of the initial ozone attack on the unsaturates. Non-stoichiometry observed in the case of acrylonitrile and ethyl acrylate has been rationalized by secondary free radical reactions. Absorptivities of the four unsaturates in vapour as well as in the solution phase have been reported. A brief attempt to study ozone-terpene reactions is also described." @default.
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- W1996308504 date "1989-01-01" @default.
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- W1996308504 title "Rate constants of the reactions of ozone with nitriles, acrylates and terpenes in gas phase" @default.
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- W1996308504 doi "https://doi.org/10.1016/0004-6981(89)90522-2" @default.
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