Matches in SemOpenAlex for { <https://semopenalex.org/work/W1996316906> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W1996316906 endingPage "5432" @default.
- W1996316906 startingPage "5426" @default.
- W1996316906 abstract "Intense (1.42 krad/min) γ-radiolysis of C60 dissolved in cyclohexane (weak magenta-colored solution) to a total dose of 51 krad resulted in the formation of a new compound (muddy red in color) with a solubility of more than 30 times that of saturated C60 in toluene. Low-power, laser desorption Fourier transform mass spectrometry (LD-FTMS) of the product yielded two ions at m/z = 1539 and 1556, which correspond to [C60(cyclohexane)10−xH]+ for x = 23 and 6, respectively. Higher power laser desorption conditions as well as collision-induced dissociation experiments of selected ions show the sequential loss of cyclohexene (C6H10) units. Small-angle X-ray scattering (SAXS) of the dissolved material supports the mass spectrometry results of cyclohexane additions to the sphere. Taken together, the mass spectrometry and SAXS data indicate that the identity of the γ-radiolysis products of C60 in cyclohexane most likely are cyclohexyl adducts of C60, primarily C60(cyclohexane)10. The SAXS data further indicate that some of the C60(C6H12)x entities aggregate into dimers in solution. A model is proposed in which cyclohexyl and hydrogen atom radiolysis products attach to C60 across double bonds. These double bonds are possibly those associated with the two top and bottom 5-fold symmetry positions around two opposing pentagons." @default.
- W1996316906 created "2016-06-24" @default.
- W1996316906 creator A5000609870 @default.
- W1996316906 creator A5002596998 @default.
- W1996316906 creator A5047967301 @default.
- W1996316906 creator A5085111378 @default.
- W1996316906 date "1996-01-01" @default.
- W1996316906 modified "2023-10-15" @default.
- W1996316906 title "Small-Angle X-ray Scattering and Mass Spectrometry Studies of γ-Irradiated C<sub>60</sub> in Cyclohexane" @default.
- W1996316906 cites W135878141 @default.
- W1996316906 cites W1977060926 @default.
- W1996316906 cites W1992161221 @default.
- W1996316906 cites W2007922419 @default.
- W1996316906 cites W2028741752 @default.
- W1996316906 cites W2058897391 @default.
- W1996316906 cites W2061636484 @default.
- W1996316906 cites W2062352774 @default.
- W1996316906 cites W2062938604 @default.
- W1996316906 cites W2076386493 @default.
- W1996316906 cites W2076583993 @default.
- W1996316906 cites W2076819213 @default.
- W1996316906 cites W2085517126 @default.
- W1996316906 cites W2092650215 @default.
- W1996316906 cites W4210994512 @default.
- W1996316906 cites W49106822 @default.
- W1996316906 cites W52631731 @default.
- W1996316906 doi "https://doi.org/10.1021/jp952374y" @default.
- W1996316906 hasPublicationYear "1996" @default.
- W1996316906 type Work @default.
- W1996316906 sameAs 1996316906 @default.
- W1996316906 citedByCount "7" @default.
- W1996316906 countsByYear W19963169062023 @default.
- W1996316906 crossrefType "journal-article" @default.
- W1996316906 hasAuthorship W1996316906A5000609870 @default.
- W1996316906 hasAuthorship W1996316906A5002596998 @default.
- W1996316906 hasAuthorship W1996316906A5047967301 @default.
- W1996316906 hasAuthorship W1996316906A5085111378 @default.
- W1996316906 hasConcept C113196181 @default.
- W1996316906 hasConcept C120665830 @default.
- W1996316906 hasConcept C121332964 @default.
- W1996316906 hasConcept C131888329 @default.
- W1996316906 hasConcept C147789679 @default.
- W1996316906 hasConcept C161790260 @default.
- W1996316906 hasConcept C162356407 @default.
- W1996316906 hasConcept C178790620 @default.
- W1996316906 hasConcept C184651966 @default.
- W1996316906 hasConcept C185592680 @default.
- W1996316906 hasConcept C191486275 @default.
- W1996316906 hasConcept C2778237882 @default.
- W1996316906 hasConcept C2779484182 @default.
- W1996316906 hasConcept C43617362 @default.
- W1996316906 hasConcept C66887884 @default.
- W1996316906 hasConceptScore W1996316906C113196181 @default.
- W1996316906 hasConceptScore W1996316906C120665830 @default.
- W1996316906 hasConceptScore W1996316906C121332964 @default.
- W1996316906 hasConceptScore W1996316906C131888329 @default.
- W1996316906 hasConceptScore W1996316906C147789679 @default.
- W1996316906 hasConceptScore W1996316906C161790260 @default.
- W1996316906 hasConceptScore W1996316906C162356407 @default.
- W1996316906 hasConceptScore W1996316906C178790620 @default.
- W1996316906 hasConceptScore W1996316906C184651966 @default.
- W1996316906 hasConceptScore W1996316906C185592680 @default.
- W1996316906 hasConceptScore W1996316906C191486275 @default.
- W1996316906 hasConceptScore W1996316906C2778237882 @default.
- W1996316906 hasConceptScore W1996316906C2779484182 @default.
- W1996316906 hasConceptScore W1996316906C43617362 @default.
- W1996316906 hasConceptScore W1996316906C66887884 @default.
- W1996316906 hasIssue "13" @default.
- W1996316906 hasLocation W19963169061 @default.
- W1996316906 hasOpenAccess W1996316906 @default.
- W1996316906 hasPrimaryLocation W19963169061 @default.
- W1996316906 hasRelatedWork W1969758957 @default.
- W1996316906 hasRelatedWork W1991529519 @default.
- W1996316906 hasRelatedWork W1997388563 @default.
- W1996316906 hasRelatedWork W2000307774 @default.
- W1996316906 hasRelatedWork W2028879825 @default.
- W1996316906 hasRelatedWork W2031791935 @default.
- W1996316906 hasRelatedWork W2043211870 @default.
- W1996316906 hasRelatedWork W2334054440 @default.
- W1996316906 hasRelatedWork W2040126539 @default.
- W1996316906 hasRelatedWork W2509858034 @default.
- W1996316906 hasVolume "100" @default.
- W1996316906 isParatext "false" @default.
- W1996316906 isRetracted "false" @default.
- W1996316906 magId "1996316906" @default.
- W1996316906 workType "article" @default.