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• W1996322425 abstract "Exploiting the hyperspherical mapping of potential energy surfaces, the evolutions of minima (valley bottoms) and saddles (ridges) as a function of the kinetic radius are identified as kinetic paths for studying reaction mechanisms and dynamics. The effect of angular momentum is investigated quantum-mechanically in a hyperspherical harmonic basis and a lower bound to adiabatic evolution is established. By a classical stability analysis, the dependence of angular momentum effects on configuration is studied. Some features of kinetic paths (such as the occurrence of symmetry degeneracies and bifurcations related to elementary catastrophes) are briefly illustrated for kinetic paths on surfaces for H3 and H3+." @default.
• W1996322425 created "2016-06-24" @default.
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• W1996322425 creator A5081837226 @default.
• W1996322425 date "1987-11-01" @default.
• W1996322425 modified "2023-09-24" @default.
• W1996322425 title "Hyperspherical analysis of kinetic paths for elementary chemical reactions and their angular momentum dependence" @default.
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• W1996322425 doi "https://doi.org/10.1016/0009-2614(87)85030-3" @default.
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