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- W1996329579 abstract "The temperature dependence of the Mossbauer doublet linewidth of tetrahedrally coordinated Fe2+ ions, distorted by the Jahn-Teller effect, was analysed by means of a new mathematical approach. The idea was that the linewidth depends on a distribution of quadrupole splittings that are in turn dependent on temperature. The variation of the quadrupole splitting was supposed to be connected with the temperature dependent population of the ground state Eg orbitals, split by the local Jahn-Teller effect. The model was applied to three sets of experimental data. The barrier splitting between the two Eg electronic states as well as their widths, , were obtained." @default.
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- W1996329579 date "2000-02-03" @default.
- W1996329579 modified "2023-09-27" @default.
- W1996329579 title "Influence of the Jahn-Teller effect on the linewidth of the Mössbauer spectra of natural spinels" @default.
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- W1996329579 doi "https://doi.org/10.1088/0953-8984/12/7/326" @default.
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