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• W1996359865 startingPage "2923" @default.
• W1996359865 abstract "The synthesis and structure of two yttrium benzene dicarboxylates, 1∝{[Y2(C12N2H8)2(C8H4O4)3]·H2O}, I and 3∝{[Y2(C12N2H8)2(C8H4O4)3]}, II, with one- and three-dimensional structure has been accomplished employing hydrothermal methods in the presence of 1,10-phenanthroline. While I is formed with phthalic aid (1,2-BDC), II is formed using isophthalic acid (1,3-BDC). Both the structures appear to have comparable building units, an eight-membered ring and a paddle-wheel arrangement, connected through the carboxylic acid. The 1,10-phenanthroline, connected to Y as a secondary ligand, occupies the inter-chain spaces in I, and projects into the channels in II. The channels in II are inter-connected. Photoluminescence studies indicate that both I and II exhibit a bathochromic shift with respect to the acids (1,2-BDC and 1,3-BDC) and a hypsochromic shift with respect to 1,10-phenanthroline. Both the compounds exhibit reasonable π⋯π interactions." @default.
• W1996359865 created "2016-06-24" @default.
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• W1996359865 date "2004-01-01" @default.
• W1996359865 modified "2023-09-23" @default.
• W1996359865 title "Synthesis, structure and luminescent properties of yttrium benzene dicarboxylates with one- and three-dimensional structure" @default.
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• W1996359865 doi "https://doi.org/10.1039/b408403a" @default.
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