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- W1996365592 abstract "Abstract Mixed micellization of cationic gemini surfactant butanediyl‐1,4‐bis(dimethyldodecylammonium bromide) with nonionic surfactants (sorbitan esters, alcohols and phenol ethoxylates) and triblock copolymers has been studied tensiometrically. Various physicochemical parameters of the studied systems including ideal CMC values, experimental and ideal micellar compositions, interaction parameters, activity coefficients of the components, etc. have been evaluated by considering theoretical models of Clint, Rubingh, Rosen and Maeda. The experimental critical micelle concentration (CMC) values of the mixed micelles were lower than the CMC values of the individual components and showed a negative deviation from ideal CMC (CMC*) values. The analysis reveals that the mole fractions of gemini are lower compared to the nonionic surfactants/triblock polymers and the values of Δ G m ° , Δ G ad ° , G min and Δ G ex m show that the spontaneity of the studied mixed micelles relatively decreases as the content of the gemini in the bulk phase increases." @default.
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- W1996365592 date "2014-01-11" @default.
- W1996365592 modified "2023-09-29" @default.
- W1996365592 title "Mixed Micellar Properties and Related Interaction Parameters of Butanediyl-1,4-bis(dodecyl dimethyl ammonium bromide) Gemini Surfactant with Nonionic Amphiphiles" @default.
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- W1996365592 doi "https://doi.org/10.1007/s11743-013-1556-z" @default.
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