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- W1996372273 abstract "The lattice parameters of two CeT 2 X 2 ( T =3d transition elements and X=Si and Ge) based Kondo lattice systems, the CeNi 2-x Cu x Si 2 and Ce(NiSi) 2-x (CuGe) x , have been studied. The analysis of the Ce-ligand distances indicates that the variation of the a-parameter dominantly affects Ce 4f-X ligandn orbital hybridization whereas the variation of c-parameter dominantly affects Ce 4f-T ligand orbital hybridization. The average Ce-ligand distance varies linearly with x across the whole series in spite of the abnormal increase of the c-parameter in the region 1.6 ≤ x ≤ 2.0. Thus, our analysis shows that the average Ce 4f-ligand orbital hybridization decreases uniformly with x across the entire range of x for the CeNi 2-x Cu x Si 2 and Ce(NiSi) 2-x (CuGe) x series. The means that the Ce 4f-ligand orbital dehybridization may not be a key factor to the formation of the heavy-fermion ground state in CeCu 2 Si 2 ." @default.
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- W1996372273 date "2002-07-30" @default.
- W1996372273 modified "2023-10-16" @default.
- W1996372273 title "Ce 4f-LIGAND DEHYBRIDIZATION IN CeT2X2-BASED KONDO LATTICE/HEAVY FERMION SYSTEMS" @default.
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- W1996372273 doi "https://doi.org/10.1142/s0217979202011378" @default.
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