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• W1996406788 abstract "A full structural study of the solid solution $x{text{BiScO}}_{3}text{ensuremath{-}}(1ensuremath{-}x){text{PbTiO}}_{3}$ (BS-PT) has been carried out by neutron powder diffraction using the General Materials Diffractometer (GEM) at ISIS facility in Oxford and complemented by in-house x-ray diffraction studies and high-temperature dielectric measurements. Atomic positions and thermal-displacement parameters have been determined by Rietveld refinement of neutron powder-diffraction data for a total of 14 different compositions of BS-PT, where $0.10ensuremath{le}xensuremath{le}0.40$. A gradual structural phase transition from a tetragonal (space group: $P4mm$) phase to a rhombohedral (space group: $R3m$) phase as a function of composition has been observed and the phase boundary is identified as a mixture of a tetragonal and a monoclinic phase with space group $Cm$. However, the refined anisotropic thermal parameters in the region $xensuremath{ge}0.39$ are found to be unrealistic for the average crystal structure and instead of a rhombohedral phase, a monoclinic phase $(Cm)$ is suggested for the compositions $xensuremath{ge}0.39$. In addition, temperature-dependent dielectric measurements have been carried out to demonstrate the physical properties of the ceramics including ferroelectric transition temperatures as a function of composition." @default.
• W1996406788 created "2016-06-24" @default.
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• W1996406788 date "2010-10-15" @default.
• W1996406788 modified "2023-10-02" @default.
• W1996406788 title "Structural investigations of the bismuth scandate-lead titanate<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi>x</mml:mi><mml:msub><mml:mrow><mml:mtext>BiScO</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub><mml:mtext>−</mml:mtext><mml:mrow><mml:mo>(</mml:mo><mml:mrow><mml:mn>1</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi></mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:msub><mml:mrow><mml:mtext>PbTiO</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub></…" @default.
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• W1996406788 doi "https://doi.org/10.1103/physrevb.82.144108" @default.
• W1996406788 hasPublicationYear "2010" @default.
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