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- W1996443024 abstract "The electrochemical behaviour of 1,2-dihydroxycyclobuten-3,4-dione (squaric acid, H2SQ) in dimethylformamide was investigated. On a Pt electrode, the reduction involves two successive, chemically reversible, one-electron processes, affording hydrogen and the basic species HSQ− and SQ2− respectively. The oxidation of SQ2− thus formed occurs in two consecutive, chemically reversible, one-electron steps, affording the radical anion SQ.− and the neutral species SQ°; the neutral species SQ° is stable in the time-scale of the voltammetric experiments only. In contrast, the chemically irreversible oxidations of H2SQ and HSQ− appear as more complicated processes. The oxidation of hydrogen in the presence of the electrogenerated basic species was also studied. A comparison with the results obtained on an Hg electrode is made and the occurrence of a different voltammetric behaviour, as regards the reduction process, is discussed briefly." @default.
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- W1996443024 title "Electrochemical behaviour of 1,2-dihydroxycyclobuten-3,4-dione in dimethyl formamide" @default.
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- W1996443024 doi "https://doi.org/10.1016/0022-0728(93)80141-4" @default.
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