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- W1996444626 abstract "The trisulfur radical anion [S3]˙− is well-known from inorganic chemistry textbooks as the blue chromophore in ultramarine blues in which this highly reactive species is trapped in a zeolitic framework. Recent findings have revealed that [S3]˙− has a multi-faceted role in a variety of media, including alkali metal–sulfur batteries, aqueous solutions at high temperatures and pressures, and ionic liquids; it has also been used to detect trace amounts of water in organic solvents. This tutorial review illustrates how various physical techniques are used to identify a reactive species in solution and shows how elucidation of electronic structures can be used to explain spectroscopic and structural properties. Examples of the function of [S3]˙− in materials science, electrochemistry, analytical chemistry and geochemistry are used to illustrate the widespread influence of this fundamentally important triatomic sulfur species." @default.
- W1996444626 created "2016-06-24" @default.
- W1996444626 creator A5015736816 @default.
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- W1996444626 date "2013-01-01" @default.
- W1996444626 modified "2023-09-25" @default.
- W1996444626 title "Ubiquitous trisulfur radical anion: fundamentals and applications in materials science, electrochemistry, analytical chemistry and geochemistry" @default.
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- W1996444626 doi "https://doi.org/10.1039/c3cs60119f" @default.
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