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- W1996455384 abstract "A new high pressure flowing afterglow apparatus with an operational pressure range of 1–20 Torr is described. The new technique has been applied in a room temperature study on the kinetics of the clustering reactions NH4+·(NH3)n + NH3 ⇄ NH4+·(NH3)n+1 for n = 0–3. The equilibrium constants and the corresponding changes in standard Gibbs free energy (ΔGpo) for these reactions were derived: Δ01Gpo = −11.2 kcal mol−1, Δ12Gpo = −9.3 kcal mol−1, Δ23Gpo = −7.0 kcal mol−1, Δ34Gpo = −4.6 kcal mol−1, where the indices indicate the number of molecules of NH3 attached to NH4+ before and after association." @default.
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- W1996455384 date "1995-11-01" @default.
- W1996455384 modified "2023-09-27" @default.
- W1996455384 title "Studies of the formation of cluster ions NH4+·(NH3)n, n = 1–4, using a high pressure flowing afterglow apparatus" @default.
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- W1996455384 doi "https://doi.org/10.1016/0168-1176(95)04259-n" @default.
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