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- W1996459721 abstract "Abstract A highly Z -selective isomerization (double bond migration) was observed when oxazolidinone vinylogous glycolate was exposed to a strong base to give N -acyl oxazolidinone, bearing an electron rich olefin. The corresponding enolate was exposed to alkyl halides to provide alkylated compounds on the γ-position with respect to OBn group, with high regioselectivity and moderate diastereoselectivity. However, the nature of the chiral oxazolidinone leads to a significant increase in the reaction diastereoselectivity. A stereospecific formation of cis -olefin was also observed in these alkylated compounds." @default.
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- W1996459721 date "2012-08-01" @default.
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- W1996459721 title "Diastereoselective alkylations of oxazolidinone vinylogous glycolates" @default.
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- W1996459721 doi "https://doi.org/10.1016/j.tetlet.2012.06.133" @default.
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