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- W1996475168 abstract "We report the first use of the Dess–Martin periodinane (DMP) for the oxidation of an arylamine to an α-dione. The methodology is illustrated by the preparation of free-base and metal chelated porphyrin-α-diones in up to 52% yield by oxidation of 2-aminoporphyrins with the DMP. We also found that DMP could be used to oxidise a 2,3-diaminoporphyrin to a porphyrin-α-dione in good yield with other free-base diaminoporphyrin isomers forming a trans-porphyrintetraone in 20% yield." @default.
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- W1996475168 date "2001-01-01" @default.
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- W1996475168 title "A new synthetic approach to porphyrin-α-diones and a -2,3,12,13-tetraone: building blocks for laterally conjugated porphyrin arrays" @default.
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- W1996475168 doi "https://doi.org/10.1039/b007389j" @default.
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