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- W1996490528 abstract "The emission spectrum of the A2Π-X2Π system of the SbO molecule has been photographed under high resolution, and the rotational structure in eight bands of the 2Π32-2Π32 component, involving v′ = 0–2 and v″ = 1–4, has been analyzed for both isotopic molecules 121SbO and 123SbO. The observed rotational lines of the corresponding 2Π12-2Π12 component are broad, with a width of about 0.2 cm−1 varying little with J. It is suggested that these broad lines represent unresolved components arising from magnetic hyperfine interaction with 121Sb or 123Sb nuclei. Isotopic shift observations contradict earlier vibrational assignments in the 2Π12-2Π12 subsystem and indicate that the A state is inverted in agreement with expectations from related systems. The principal molecular constants (in cm−1) obtained for 121SbO are StateTeωeωeχeBe103αe107DeX2Π120818.74.2———X2Π32x ≈ 2272814.14.30.359202.382.8A2Π1221 467.4565.82.9———A2Π32x + 18 521.7570.42.60.288561.822.9 RKR potential curves have been determined. Franck-Condon factors calculated from these curves show excellent agreement with the observed relative intensities." @default.
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- W1996490528 date "1984-05-01" @default.
- W1996490528 modified "2023-09-26" @default.
- W1996490528 title "The A2Π-X2Π system of the SbO molecule" @default.
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- W1996490528 doi "https://doi.org/10.1016/0022-2852(84)90115-2" @default.
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