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- W1996507681 abstract "Gold nanoparticles of various sizes, supported onto ceria, were synthesized using both deposition−precipitation and coprecipitation methods. Whatever the size, the study of the Au/CeO2 interface confirms the existence of two preferential orientation relationships with a dislocation network which compensates the 25% interfacial lattice mismatch. Behaviors of supported gold nanostructures under the electron beam were examined by high-resolution transmission electron microscopy (HRTEM). The thermal stability of the gold nanostructures was found to be strongly affected by the particle size. For small nanostructures (<5 nm), reversible shrinkage of gold layer by layer onto ceria surface was observed. For larger ones, a progressive and irreversible encapsulation by a CeO2−x layer was found and a four-step process was experimentally underlined." @default.
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- W1996507681 date "2009-04-30" @default.
- W1996507681 modified "2023-10-18" @default.
- W1996507681 title "Size-Dependent Stability of Supported Gold Nanostructures onto Ceria: an HRTEM Study" @default.
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- W1996507681 doi "https://doi.org/10.1021/jp9001115" @default.
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