Matches in SemOpenAlex for { <https://semopenalex.org/work/W1996540322> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W1996540322 endingPage "4092" @default.
- W1996540322 startingPage "4090" @default.
- W1996540322 abstract "The reactions of (4-methoxyphenyl)boronic acid (1a) and of (2,6-dimethylphenyl)boronic acid (1b) with (PMe(3))(3)Rh-(OC(6)H(4)Me-4) (2) in a 5:1 molar ratio result in the formation of cationic rhodium complexes with new tetraarylpentaborates [Rh(PMe(3))(4)](+)[B(5)O(6)Ar(4)](-) (3a, Ar = C(6)H(4)OMe-4; 3b, Ar = C(6)H(3)Me(2)-2,6). The characterization of 3a is as follows: orthorhombic space group P2(1)2(1)2(1), a = 14.7600(5) A, b = 17.1675(5) A, c = 19.8654(5) A; V = 5033.7(3) A(3); Z = 4. The characterization of 3b is as follows: orthorhombic space group Pnma, a = 23.704(6) A, b = 17.254(8) A, c = 13.304(2) A; V = 5441(2) A(3); Z = 4. An intermediate complex, [Rh(PMe(3))(4)](+)[Ph(3)B(3)O(3)(OC(6)H(4)Me-4)](-) (4), was isolated from the reaction of phenylboroxine, (PhBO)(3), with 2. The tetraarylpentaborates smoothly undergo hydrolysis to give [Rh(PMe(3))(4)](+)[B(5)O(6)(OH)(4)](-) (5)." @default.
- W1996540322 created "2016-06-24" @default.
- W1996540322 creator A5010926450 @default.
- W1996540322 creator A5059240429 @default.
- W1996540322 creator A5088181080 @default.
- W1996540322 date "2002-07-11" @default.
- W1996540322 modified "2023-09-23" @default.
- W1996540322 title "Tetraarylpentaborates, [B<sub>5</sub>O<sub>6</sub>Ar<sub>4</sub>]<sup>-</sup> (Ar = C<sub>6</sub>H<sub>4</sub>OMe-4, C<sub>6</sub>H<sub>3</sub>Me<sub>2</sub>-2,6): Their Formation from the Reaction of Arylboronic Acids with an Aryloxorhodium Complex, Structure, and Chemical Properties" @default.
- W1996540322 cites W1972580049 @default.
- W1996540322 cites W1978890358 @default.
- W1996540322 cites W2006516825 @default.
- W1996540322 cites W2019270500 @default.
- W1996540322 cites W2021266223 @default.
- W1996540322 cites W2025266309 @default.
- W1996540322 cites W2031818119 @default.
- W1996540322 cites W2050626017 @default.
- W1996540322 cites W2075030802 @default.
- W1996540322 cites W2096184132 @default.
- W1996540322 cites W2125226084 @default.
- W1996540322 cites W2161805950 @default.
- W1996540322 cites W2166178695 @default.
- W1996540322 cites W2951795214 @default.
- W1996540322 cites W2952423535 @default.
- W1996540322 doi "https://doi.org/10.1021/ic015630w" @default.
- W1996540322 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12160390" @default.
- W1996540322 hasPublicationYear "2002" @default.
- W1996540322 type Work @default.
- W1996540322 sameAs 1996540322 @default.
- W1996540322 citedByCount "18" @default.
- W1996540322 countsByYear W19965403222012 @default.
- W1996540322 countsByYear W19965403222013 @default.
- W1996540322 countsByYear W19965403222015 @default.
- W1996540322 countsByYear W19965403222016 @default.
- W1996540322 countsByYear W19965403222021 @default.
- W1996540322 countsByYear W19965403222022 @default.
- W1996540322 crossrefType "journal-article" @default.
- W1996540322 hasAuthorship W1996540322A5010926450 @default.
- W1996540322 hasAuthorship W1996540322A5059240429 @default.
- W1996540322 hasAuthorship W1996540322A5088181080 @default.
- W1996540322 hasConcept C115624301 @default.
- W1996540322 hasConcept C161790260 @default.
- W1996540322 hasConcept C178790620 @default.
- W1996540322 hasConcept C183882617 @default.
- W1996540322 hasConcept C185592680 @default.
- W1996540322 hasConcept C2994067411 @default.
- W1996540322 hasConcept C37243968 @default.
- W1996540322 hasConcept C521398313 @default.
- W1996540322 hasConcept C55493867 @default.
- W1996540322 hasConcept C71240020 @default.
- W1996540322 hasConcept C8010536 @default.
- W1996540322 hasConcept C94412978 @default.
- W1996540322 hasConceptScore W1996540322C115624301 @default.
- W1996540322 hasConceptScore W1996540322C161790260 @default.
- W1996540322 hasConceptScore W1996540322C178790620 @default.
- W1996540322 hasConceptScore W1996540322C183882617 @default.
- W1996540322 hasConceptScore W1996540322C185592680 @default.
- W1996540322 hasConceptScore W1996540322C2994067411 @default.
- W1996540322 hasConceptScore W1996540322C37243968 @default.
- W1996540322 hasConceptScore W1996540322C521398313 @default.
- W1996540322 hasConceptScore W1996540322C55493867 @default.
- W1996540322 hasConceptScore W1996540322C71240020 @default.
- W1996540322 hasConceptScore W1996540322C8010536 @default.
- W1996540322 hasConceptScore W1996540322C94412978 @default.
- W1996540322 hasIssue "16" @default.
- W1996540322 hasLocation W19965403221 @default.
- W1996540322 hasLocation W19965403222 @default.
- W1996540322 hasOpenAccess W1996540322 @default.
- W1996540322 hasPrimaryLocation W19965403221 @default.
- W1996540322 hasRelatedWork W1192677903 @default.
- W1996540322 hasRelatedWork W1570576037 @default.
- W1996540322 hasRelatedWork W1970018419 @default.
- W1996540322 hasRelatedWork W1982537157 @default.
- W1996540322 hasRelatedWork W2375172335 @default.
- W1996540322 hasRelatedWork W2378541949 @default.
- W1996540322 hasRelatedWork W2385346660 @default.
- W1996540322 hasRelatedWork W2952057360 @default.
- W1996540322 hasRelatedWork W2952271444 @default.
- W1996540322 hasRelatedWork W2952727089 @default.
- W1996540322 hasVolume "41" @default.
- W1996540322 isParatext "false" @default.
- W1996540322 isRetracted "false" @default.
- W1996540322 magId "1996540322" @default.
- W1996540322 workType "article" @default.