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- W1996553985 abstract "Experimental studies of the diffusion of moderate molecular weight drugs through synthetic polymeric membranes has led us to define a new parameter to characterize solute permeation. The accepted parameter which describes trans-membrane flux is permeability, P, defined as the product of the flux times the membrane thickness divided by the concentration difference across the membrane in the external solution. The parameter described here is called transference, T̄, and is defined as the mass of solute transferred from a saturated solution, under perfect sink conditions, across the membrane per unit time and area, multiplied by the thickness of the membrane. p]Regardless of whether there is solvent—membrane interaction or not, the permeability coefficient, P, for a given solute and membrane differs from one solvent to another. In contrast, transference is independent of solvent, unless there is solvent—membrane interaction, in which case the inconsistency of transference for a particular solvent signifies that the membrane is modified by the presence of that solvent or solvent—solute combination, It is for these reasons that transference is a more comprehensive parameter than permeability, and is basic at the same time to solute—membrane permeation. p]When transference is introduced into Fick's taw it is immediately obvious that the flux of solute through the membrane, at equal fraction of saturation in any donor solvent, is equal and independent of the donor solvent in the absence of solvent—membrane interaction, when the solute has a constant solvent—membrane partition coefficient. p]Two examples of the use of the transference parameter are provided." @default.
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- W1996553985 title "Transference: a comprehensive parameter governing permeation of solutes through membranes" @default.
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- W1996553985 doi "https://doi.org/10.1016/s0376-7388(00)82254-1" @default.
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