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- W1996564449 abstract "This work confirms that the activities of individual ions measured with ion-selective electrodes are physically meaningful. The individual activities of the Cl−, Na+ and K+ ions in single-electrolyte aqueous solutions of HCl, NaOH and KOH were measured at 298.2 K in the range from 0 to 2 molal. In the pH range from 1 to 13, the pH values calculated from the measured activities of the ions are in good agreement with the values obtained with a pH probe. In agreement with previous results for potassium ions, and opposite to the behavior of other cations in 1:1 electrolyte solutions, the K+ and the H+ ions were found to have smaller activities than their conjugate anions. The experimental activity coefficients of the ions were correlated with the Khoshkbarchi-Vera equation and with the New Hydration Theory, and compared with the predictions given by the Pitzer theory." @default.
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- W1996564449 date "2001-12-01" @default.
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- W1996564449 title "Determination of the activity of H+ ions within and beyond the pH meter range" @default.
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- W1996564449 doi "https://doi.org/10.1002/aic.690471218" @default.
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